Expansion 6.0 Unlock
The following is where to unlock the Expansion 6.0 main items (all are the starting quest):
MSQ:
    The Next Ship to Sail
Rising Stones (X: 6.0, Y: 5.9)- Alphinaud
Role Quest:
Tank Quests:
    Shrouded in Peril
    Radz-at-Han (X: 7.6, Y: 9.7)- Gridanian Delegate
Melee Quests:
    Storm Clouds Brewing
Radz-at-Han (X: 7.7, Y: 9.6)- Limsa Lominsan Delegate
Physical Range
    Seeds of Disquiet
Radz-at-Han (X: 7.6, Y: 9.4)- Doman Delegate
Magical Range
    Our Aching Souls
Radz-at-Han (X: 7.8, Y: 9.4)- Ishgardian Delegate
Healer
    Far from Free
Radz-at-Han (X: 7.5, Y: 9.6)- Ala Mhigan Delegate
Studium Deliveries
    Requires: Disciple of Hand or Land at level 80
    The Faculty
    Old Sharlayn (X: 4.0, Y: 9.4)
Ishgard Housing Ward
    Ascending to Empyreum
    Foundation (X: 9.9, Y: 11.8)- Gondelimbaud
Hunts for New Areas
    Requires: War or Magic Job at level 80
    The Hunt for Specimens
    Old Sharlayan (X: 11.2, Y: 12.0)- Diminutive Gleaner
Stone, Sky, Sea
Requires: War or Magic Job at level 90
    A Place to Train
Radz-at-Han (X: 12.3, Y: 10.7)- Hardy-looking Radiant
New Jobs
Requires: War or Magic Job at level 70
    Reaper Job
        The Killer Instinct
        Ul'dah- Steps of Nald (X: 12.8, Y: 8.6)- Flustered Attendant
    Sage Job
        Sage's Path
        Limsa Lominsa Lower Decks (X: 9.4, Y: 12.9)- Sharlayan Maiden